Cell EMF and Thermodynamics
Electrochemical Buffer Volume
A volume of x mL of 5 M NaHCO
3 solution was mixed with 10 mL of 2 M H
2CO
3 solution to make an electrolytic buffer. If the same buffer was used in the following electrochemical cell to record a cell potential of 235.3 mV, then the value of x = _________ mL (nearest integer).
Sn(s) |

(0.5 M) |

(0.05 M) | OH
– | Bi
2O
3(s) | Bi(s)
Consider upto one place of decimal for intermediate calculations
